Fundamental Coordination Ability of s-Block Metal Ions

Part I: Chemical interaction above electrostatic force between s-block metals and ligand ions

1. Host-Guest Chemistry of s-Block Metal Ions and the Development of Supramolecule Chemistry

Part II: The Development of Supramolecular Chemistry Systems

2. Light Metal Coordination Polymers

3. Voltammetric Studies on Chemical Interactions of Alkali Metal Ions with Acetate and Benzoate Ions in Acetonitrile

4. Salt Effects on Proton Transfer from Nitrophenols to Amine or Pyridine Bases in Acetonitrile

5. Elucidation of Salt Effects on the Indicator Acidity in Acetonitrile

6. Direct Chelate Formation between Alkaline Earth Metal Ions and 1-(2-Pyridylazo)-2-naphthol and Related Reactions in Acetonitrile

7. Higher Ion–Aggregates in Low Permittivity Media

8. Conductivity and Spectroscopic Studies of Ion Aggregates in Higher Permittivity Media

Part III: Coordination phenomena of s-block metal ions in aprotic and protic solvents

9. UV–Visible and {sup|1}H or {sup|13}C NMR Spectroscopic Studies on the Specific Interaction between Lithium and Tropolonate Ions in Acetonitrile or Other Solvents

10. Interaction between Protons or Alkaline Earth Metal Ions and the Benzoate Ion in Acetonitrile Studied by UV–visible, {sup|1}H and {sup|13}C NMR Spectroscopy

11. Precipitation and Re-Dissolution of s-Block Metal Salts Based on Coordination and “Reverse Coordination” with Aromatic Dicarboxylate, Sulfonate, or Disulfonate ions in Acetonitrile

12. Specific Coordination Phenomena of Alkaline Earth Metal Ions with Mono-, Di-, and Trisulfonates in Alcohols and Binary Solvents

13. Strong Complexing Ability of Alkali Metal and Alkaline Earth Metal Ions with Organic Phosphinate and Phosphates

14. Chemical Interaction between Alkaline Earth Metal Ions and the Benzoate or 2,6-Naphthalenedicarboxylate Ion in Acetonitrile and Alcohols

15. Coordination and “Reverse Coordination” of Alkali Metal, Alkaline Earth Metal, and Indium Ions with 1,3,6-Naphthalenetrisulfonate Ion in Protic and Aprotic Solvents

Part IV: Application of the coordination ability of s-block metals and related reactions in solution

16. {sup|1}H and {sup|13}C NMR Detection of the Carbocations or Zwitterions from Fluoran Leuco Dyes or Trityl Chlorides on the Addition of s-Block Metal Ions

17. Alternative Mechanism of S{sub|N}1 Solvolysis Based on the Direct Chemical Interaction between s-Block Metal Cations and Leaving–Group Anions

18. Discovery of Enhanced Oxidation Mechanism of Dilute Nitric Acid (and Pure Gold Dissolution in Seawater)

19. Pure Gold Dissolution by the Oxidation Ability of Dilute Nitric and Nitrous Acids in the Presence of Abundant Metal Salts

20. Pure Gold and Stainless Steel Dissolution or Corrosion in Dilute Halic Acids (HXO{sub|3}, X = Cl, Br, I) Solution containing Abundant Halide Ions

21. Elucidation of Specific Ion Association in Nonaqueous Solution Environments